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Solution properties of polystyrene prepared under high pressure (1954)

Trementozzi, Q. A. ; Buchdahl, R.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 12 (1954), S. 149-154

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The molecular weight, the size, and the second virial coefficient have been determined for a series of styrene polymers prepared under high pressure (0 to 4000 atmospheres) using light scattering techniques. The intrinsic viscosity-molecular weight relationship, the size-molecular weight relationship, and the magnitude of the second virial coefficient reveal no significant differences when compared to similar data of regular polystyrene. Structural differences due to the method of polymerization do not exist to the extent that they can be revealed by such measurements.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1954.120120112

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