ISSN:
0022-3832
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Using the cellulose glycolic acid ethers of various etherification degrees as a sample of high-molecular weak electrolytes, investigations were carried out on some problems on the dissociation equilibrium, such as the influence of sample concentration, distribution density of electrolyte radicals, the salt effect, and the effect of neutralization reagents. The experimental data were treated by means of the modified Kern's dissociation formula (1) and Kagawa's formula (2). (1)$$ \frac{{a_{\rm H} \cdot \alpha }}{{1 - \alpha }} = K = K_s \left( {\frac{{1 - \alpha }}{\alpha }} \right)^m $$ (2)$$ \frac{{a_{\rm H}^2 }}{{C_{\rm P} (1 - \alpha )}} = k = k_s \left( {\frac{{1 - \alpha }}{\alpha }} \right)^n $$ The results obtained were discussed with Kagawa's opinion on the fixation of counterions.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1951.120070108
