ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
It has been shown that 6-chloro sugar derivatives are thermally less stable than the corresponding unsubstituted carbohydrates. When heated, they generate hydrogen chloride which catalyzes a series of heterolytic reactions including transglycosylation, dehydration, inter- and intramolecular etherification, and condensation. The latter products are ultimately carbonized through free-radical reactions producing large amounts of char.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1976.070200113