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Soluble high polymers from allyl methacrylate (1968)

Higgins, J. P. J. ; Weale, K. E.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-1: Polymer Chemistry 6 (1968), S. 3007-3013

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ISSN: 0449-296X

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Allyl methacrylate has been polymerized by free-radical methods and found to yield a soluble polymer in carbon tetrachloride, dioxane, and diallyl ether solutions. The overall rate equation in diallyl ether is Rp = k[ln]0.7[M]1.6. It is suggested that propagation and cyclization reactions proceed only via addition to the methacrylyl groups of the monomer. Some degradative chain transfer occurs with the allyl groups, and it is considered that the solvents may ensure the production of soluble polymers by reactions in which allyl-radical side chains are terminated without crosslinking.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1968.150061105

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