ISSN:
0449-2978
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
A method for the determination of the molecular weight spread in the narrow peaks in the GPC chromatograms of nitric acid-degraded polyethylene is presented. It is found that polar endgroups added to the polymer chains during scission cause the peaks to be broader than those of paraffins with the same molecular weight spread. After allowing for this extra instrumental broadening, estimates are made of the molecular weight spread for unannealed and annealed single crystals of polyethylene and bulk polyethylene as a function of degradation time. It is proposed that after long degradation times the molecular weight spread is a measure of fluctuations in the original crystalline lamellar thickness.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1970.160080103
