ISSN:
0449-2978
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
A modus operandi is developed for determining the molecular structure of hydroxypropylcellulose (HPC), and characterizing, in quantitative terms, the morphological changes occurring when a water-cast film of the polymer is deformed. This involves the application of the following eleven different physical measurements: wide-angle x-ray diffraction, differential scanning calorimetry, density, melt rheometry, infrared spectroscopy, refractive index, birefringence, sonic modulus, small-angle light scattering, optical and electron microscopy. In addition, a computer was utilized as a mathematical diffractometer. Morphologically, water-cast HPC was observed to have structure at all levels, from the molecular to the supermolecular. The HPC molecule has a backbone of anhydroglucose units twisted into an irregular 31 helix. Intramolecular hydrogen bonding of the poly(propylene oxide) side chains leads to a stiff, rodlike molecule. The molecules are packed into microfibrillar crystallites 470 Å long and 34 Å in diameter. The microfibrils in turn, associate into supermolecular rodlike structures. The structural rearrangements that occur at each morphological level during deformation of HPC film are quantitatively examined and described.
Additional Material:
36 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1969.160070705
