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Wideline NMR studies of oriented nylon 66 under tensile stress (1966)

McMahon, P. E.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 501-505

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ISSN: 0449-2978

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: NMR linewidth studies of nylon 66 as a function of temperature and applied tensile stress have been conducted. The principal motional transition temperature was found to be shifted to higher temperatures with stress application by 9°C./g./den. At any given temperature, increased stress resulted in an increased linewidth. An attempt was made to correlate the shift in the motional transition temperature with the concept that a segment experiencing motion must do work against the applied tensile stress.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1966.160040318

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