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Syndiospecific polymerization of styrene using methylaluminoxane-activated bis(phenolato)titanium complexes (1998)

Okuda, Jun ; Masoud, Emad

Weinheim : Wiley-Blackwell

Macromolecular Chemistry and Physics 199 (1998), S. 543-545

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ISSN: 1022-1352

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Styrene was polymerized using a series of methylaluminoxane-activated bis(phenolato)titanium complexes of the type {(OC6H2-4-Me-6-tBu)2Z}Tix2 (X = Cl, OiPr, η5-C5Me5) to give syndiotactic polystyrene. Catalyst activity was found to depend on the nature of the bridging group Z, where Z = CH2, CH2CH2, S, S=O. Activity was found to be highest for Z = S.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

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