ISSN:
1022-1352
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Free-radical copolymerization at 50°C of butyl acrylate with methyl methacrylate was carried out in benzene solution using 3 and 5 mol/L as the overall concentration of monomers. Both the reactivity ratios and the rate coefficients of copolymerization are affected by the total monomer concentration. Reactivity ratios were analyzed on the basis of the “bootstrap” model, and the copolymerization rate is interpreted assuming a penultimate effect upon the propagation reaction.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1996.021971120