ISSN:
1022-1352
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Aliphatic homopolyesters and copolyesters based on 1,3-propanediol and containing terephthalic acid as aromatic compounds and sebacic acid as aliphatic compound were synthesized by condensation in bulk. Intrinsic viscosity and weight-average molecular weight were measured. Melting temperatures were studied by differential scanning calorimetry. For all polyesters the biodegradability was tested. Test media were inoculated with either municipal compost eluates or decanted sewage sludge. Criteria measured were visible changes, weight loss, and scanning electron microscopy indicating the visible changes of the surface. Compositions of copolyesters were characterized by 13C NMR spectroscopy. As a major result it is concluded that biodegradability depends substantially on the sequential structure of the polymer.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1994.021950235