ISSN:
1022-1352
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Racemic and optically active protected glycidols (as 1-ethoxyethyl ethers) are readily polymerized with anionic initiators (e.g., CsOH). Polymers with molecular weights up to 30 000 are obtained without cleavage of the protective group. Oligomers (degree of polymerization [DPn] 5 to 10) are prepared using an aluminium complex derived from a Schiff's base. The protected thioglycidol (synthesized from the protected glycidol) leads to very high-molecular-weight polymers (150 000-320 000) using anionic or anionic coordinated initiators. Copolymers of protected glycidol with ethylene oxide are obtained with KOH as initiator. Regeneration of hydroxyl groups in polymers is carried out with acidic cleavage. Treatment of protected polyglycidol with formic acid leads first to the formate of polyglycidol. Then, after saponification, pure polyglycidol is obtained. The use of aqueous hydrochloric acid leads directly to the free polymer.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1994.021950111
