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Amphiphilic liquid-crystalline networks - phase behavior and alignment by mechanical fields (1995)

Fischer, Peter ; Schmidt, Claudia ; Finkelmann, Heino

Weinheim : Wiley-Blackwell

Macromolecular Rapid Communications 16 (1995), S. 435-447

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ISSN: 1022-1336

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: A cross-linked polysiloxane carrying non-ionic amphiphilic side-groups attached with their hydrophobic end to the polymer backbone is synthesized. The amphiphilic groups are selectively deuterated at the α-position of the hydrophobic alkyl chains. The phase behavior with water is studied by deuterium nuclear magnetic resonance spectroscopy. A lamellar phase (La) is observed on the low-water-concentration side of the liquid-crystalline regime. The domains of the La-phase can be aligned macroscopically by uniaxial compression of the sample.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/marc.1995.030160605

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