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Polymerization of water-in-oil microemulsions: Methyl methacrylate, acrylic acid, and sodium acrylamidostearate (1985)

Chew, C. H. ; Gan, L. M.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 2225-2232

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Water-in-oil (w/o) microemulsions of methyl methacrylate (MMA), acrylic acid (AA), sodium acrylamidostearate (NaAAS), and water were investigated. MMA, AA, and NaAAS could be terpolymerized in these microemulsions. For a composition of 54% MMA, 34% AA, 2% NaAAS, and 10% H2O, polymers of high molecular weights of about 1,000,000 were obtained between 3.5 to 24% polymer conversion. The system became a transparent gel when conversion exceeded 36%. Transparent solid terpolymer containing water up to 16% were also obtained after fully polymerizations of certain compositions.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1985.170230812

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