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Cation radical cycloaddition polymerization: Diels-Alder copolymerization (1998)

Bauld, Nathan L. ; Aplin, J. Todd ; Yueh, Wang ; [et al.]

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 11 (1998), S. 825-830

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ISSN: 0894-3230

Keywords: cation radical cycloaddition polymerization ; Diels-Alder copolymerization ; Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The Diels-Alder cycloaddition copolymerization of a bis(diene) with ionizable bis(dienophiles) via a cation radical mechanism has been accomplished using tris(4-bromophenyl)aminium hexachloroantimonate as a catalyst in dichloromethane solvent. The reactions occur at 0°C and yield Diels-Alder polymers of MW up to ca. 10,000 and a polydispersity index ca. 2. © 1998 John Wiley & Sons, Ltd.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

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