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Vibrational spectra of C4H7+ isomers in low-temprature antimony pentafluoride matrices (1993)

Vančik, H. ; Gabelica, V. ; Sunko, D. E. ; [et al.]

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 6 (1993), S. 427-432

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The IR spectra of isomeric bicyclobutonium (1), delocalized cyclopropylcarbinyl (2) and 1-methylally (3) cations were recorded at 180 K in SbF5 matrices. Cations 1 and 2 generated from cyclopropylcarbinyl and cyclobutyl chloride, respectively, rearrange to 3 at temperatures above 230 K. The structures 1, 2 and 3 were confirmed by comparison of the recorded frequencies with the MP2/6-31G*-calculated values. These results are in accord with prediction that ions 1 and 2 are rapidly equilibrating non-classical structures.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610060708

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