ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
4-Cyano-1-(7-carboxyheptadecyl)pyridinium bromide (CCHP) was synthesized using standard procedures. The rates and product distribution of the reaction between OH- ion and CCHP are very similar to those previously obtained with alkyl-substituted 4-cyanopyridinium ions. The effect of hexadecyltrimethylammonium bromide micelles on the rate and product distribution of CCHP indicated that the cyanopyridinium ring of this compound is distal to the surface of the micelle. CCHP constitutes a probe for ionic composition in the vicinity of positively charged micelles.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610041010