ISSN:
0044-2313
Keywords:
α-Functionalized methylphenyl phosphines
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
α-Functionalized 2-Methylphenyl Phosphines, 2-(HE—CH2)—C6H4—PH2 (E: O, NR, PH) I. Preparation, Deprotonation and Silylation BehaviourBy reaction of different ortho-substituted phenyl phosphonates 2-X—C6H4—PO3R2 (X = COOR, CONHR, PO3R2) with LiAlH4 α-functionalized 2-methylphenyl phosphines 2-(HE—CH2)—C6H4—PH2 (E: O, NPh, PH) are accessible. The title compounds are characterized by deprotonation and silylation experiments.
Notes:
Durch Reduktion verschieden ortho-substituierter Benzolphosphonsäureester 2-X—C6H4—PO3R2 (X = COOR, CONHR, PO3R2) mit LiAlH4 werden die α-funktionellen 2-Methylphenylphosphane 2-(HE—CH2)—C6H4—PH2 (E: O, NPh, PH) zugänglich. Deren Metallierungs- und Silylierungsverhalten wird 31P-NMR-spektroskopisch untersucht.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19946201205
