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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 554 (1987), S. 137-145 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Concerning Polymetaarsenites. Preparation and Crystal Structure of BaAs2O4. H2OBaAs2O4·H2O was prepared by hydrothermal reaction of BaO with As2O3 at a temperatur of 200°C. An X-ray structural analysis demonstrated that the phase contains polymetaarsenite anions [As4O84-]n, which adopt vierer single chains in the lattice. The relationship between the conformation of metaarsenite chains and cation size is discussed.
    Notes: BaAs2O4·H2O wurde durch hydrothermale Reaktion von BaO mit As2O3 bei einer Temperatur von 200°C dargestellt. Eine Röntgenstruktranalyse ergab, daß die Phase Polymetaarsenitanionen [As4O84-]n beinhaltet, die im Kristallgitter als Vierer-Einfachketten vorliegen. Die Beziehung zwischen Konformation von Polymetaarsenitketten und Kationgröße wird erlätert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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