ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Coordination Compounds of Aminoacridine-N-oxides with Thiocyanates of the 3d Metals.Reactions of thiocyanates of the 3d metals with selected aminoacridine-N-oxides in homogeneous dilutions of N,N-dimethylformamide form compounds of the type [M(AAcNO)a(DMF)b(NCS)2] · cDMF and [M′(AAcNO)d(DMF)e(NCS)3] · fDMF, M = Mn2+, Co2+, Ni2+, Cu2+, Zn2+; M′ = Cr3+, Fe3+; AAcINO = 3,6-diamino-2,7-dimethylacridin-N-oxide, AAcIINO = 3,6-bis(dimethylamino)acridin-N-oxide, AAcIIINO = 2-ethoxy-6,9-diaminoacridin-N-oxide; a = 1, 2, 3, 4; b = 0, 1; c = 0, 1, 2, 3; d = 1, 2, 3; e = 0, 1, 2; f = 0, 1, 2, 3.The complexes are characterized by IR (4000-200 cm-1) and UV-VIS spectra in solutions and solids and by EPR and conductivity investigations.
Notes:
Reaktionen von Metallthiocyanaten der 3d-Reihe mit ausgewählten Aminoacridin-N-oxiden führen aus homogenen N,N-Dimethylformamidlösungen zu Verbindungen der Typen [M(AAcNO)a(DMF)b(NCS)2] · cDMF und [M′(AAcNO)d(DMF)e(NCS)3] · fDMF, M7dbond;Mn2+, Co2+, Ni2+, Cu2+, Zn2+; M′ = Cr3+, Fe3+; AAcINO = 3,6-Diamino-2,7-dimethylacridin-N-oxid, AAcIINO = 3,6-Bis(dimethylamino)acridin-N-oxid, AAcIIINO = 2-Ethoxy.6,9-diaminoacridin-N-oxid; a = 1, 2, 3, 4; b = 0, 1; c = 0, 1, 2, 3; d = 1, 2, 3; e = 0, 1, 2 und f = 0, 1, 2, 3.Die dargestellten Komplexe werden durch die IR (4000-200 cm-1) und UV-VIS-Spektren von Lösungen und Festkörpern sowie durch EPR- und Leitfähigkeitsuntersuchungen näher charakterisiert.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19855291026
