ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On the Coordination Chemistry of Phosphines and Phosphine Oxides. XXVIII. Transition Metal Aminoalkylphosphine Complexes. Part II: Palladium and Platinum ComplexesAminoalkylphosphines - C6H5HP—CH2 · CH2—, (C6H5)2P—CH2 · CH2 · CH2—NH2, (C6H5)2P—CH2 · CH2 · CH2—N=CHC6H5 - react with palladium and platinum salts to give coordination compounds of the type MX2, MX2()2, and MX2()4 (M = Pd, Pt; X = Cl, BPh4). The chelating activity of the ligands, structure and properties of the metal complexes are discussed.
Notes:
Aminoalkylphosphine - C6H5HP—CH2 · CH2—, (C6H5)2P—CH2 · CH2 · CH2—NH2, (C6H5)2P—CH2 · CH2 · CH2—N=CHC6H5 - reagieren mit Palladium- sowie Platin(II)-Salzen zu Koordinationsverbindungen des Typs MX2, MX2()2 und MX2()4 (M = Pd, Pt; X = Cl, BPh4). Chelataktivität der -Liganden, Struktur und Eigenschaften der Komplexe werden diskutiert.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19804640116
