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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 450 (1979), S. 70-78 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: NMR Investigations on Dimeric Dialkylthallium Compoounds with (TIX)2 Four-membered Ring StructureNMR investigations on dimeric dialkylthallium amides and on dimethylthallium diphenylphosphide indicate a significant influence of the largeness of the bridging groups on the binding strength in the (TIX)2-four-membered ring structure. Exchange reactions among different dimeric dialkylthallium compounds give evidence of a dimer-monomer equilibrium, which is of fundamental importance for the reactivity and the reaction mechanisms of these compounds.
    Notes: NMR-Untersuchungen an dimeren Dialkylthalliumamiden und am Dimethylthalliumdiphenylphosphid indizieren einen signifikanten Einfluß der Größe der Brückengruppen auf die Bindungsstärke in den (TIX)2-Vierringen. Austauschreaktionen zwischen unterschiedlichen dimeren Dialkylthalliumverbindungen beweisen ein Dimer-Monomer-Gleichgewicht, das von grundsätzlicher Bedeutung für die Reaktivität und die Reaktionsmechanismen dieser Verbindungen ist.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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