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Über Oxocuprate. XIX. Ein Oxohalogenocuprat(I): Ba2CuO2Cl (1977)

Kipka, R. ; Müller-Buschbaum, Hk.

Weinheim : Wiley-Blackwell

Zeitschrift für anorganische Chemie 430 (1977), S. 250-254

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ISSN: 0044-2313

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: On Oxocuprates. XIX. The Oxohalogenocuprate(I): Ba2CuO2ClThe hitherto unknown compound Ba2CuO2Cl was prepared and examined by single crystal X-ray diffractometer investigation (a = 983.5 pm, α = 25,04°; Space group D53d—R3m). Cu+ has the coordination O—Cu—O, Ba2+ an octahedral surrounding. A discussion of the structure is given.

Notes: Ba2CuO2Cl wurde neu dargestellt und an Einkristallen röntgenographisch untersucht (a = 983,5 pm, α = 25,04°; Raumgruppe D53d—R3m). Cu+ besitzt hantelförmige Koordinationspolyeder, die längs [001] die in Doppelschichten angeordneten Oktaeder um Ba2+ verknüpfen.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/zaac.19774300124

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