ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Experiments on the Oxidative Addition of Thionylhalides to Transition Metal ComplexesThe complexes [(C6H5)3P]4Pd and [(C6H5)3P]2Ni(NO)Cl react with SOX2 to trans [(C6H5)3P]2PdX2 (X = Cl, Br) resp. to [(C6H5)3PX][NiX3] (X = Cl). Furthermore (C6H5)3PO and (C6H5)3PS are formed. In contrast SOCl2 is added oxidatively by [(C6H5)3P]2Ir(CO)Cl to the complex [(C6H5)3P]2Ir(CO)(Cl2)SOCl.
Notes:
Die Komplexe [(C6H5)3P]4Pd und [(C6H5)3P]2Ni(NO)Cl reagieren mit SOX2 zu trans-[(C6H5)3P]2PdX2 (X = Cl. Br) bzw. [(C6H5)3PX][NiX3] (X = Cl). Weiterhin bilden sich (C6H5)3PO und (C6H5)3PS. Im Gegensatz dazu wird SOCl2 durch [(C6H5)3P]2 Ir(CO)Cl oxydativ zu dem Komplex [(C6H5)3P]2 Ir(CO)(Cl2)SOCl addiert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19754150202
