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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 375 (1970), S. 72-76 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The molecular spectra of (C6H5)3GeSC6H5 (I), (C6H5)3SnSC6H5 (II), (C6H5)2 · Sn(SC6H5)2 (III) and (C6H5)3PbSC6H5 (IV) are reported and the metal-sulfur vibrational frequencies assigned. The positions of these frequencies are compared with those of the vSn-O and vSn-Se in (C6H5)3SnOC6H5 (V) and (C6H5)3SnSeC6H5 (VI).The bonding nature is discussed in connection with other similar organometal sulfides.
    Notes: Die Molekülspektren von (C6H5)3GeSC6H5 (I), (C6H5)3SnSC6H5 (II), (C6H5)2Sn(SC6H5)2 (III) und (C6H5)3PbSC6H5 (IV) werden mitgeteilt und die Metall-Schwefel-Valenzschwingungen zugeordnet. Die Lage dieser Frequenzen wird mit der der vSn—O und vSn—Se in (C6H5)3SnOC6H5 (V) und (C6H5)3SnSeC6H5 (VI) verglichen. Im Zusammenhang mit früheren Untersuchungen an ähnlich gebauten Organometallsulfiden werden die Bindungsverhältnisse diskutiert.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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