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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The new isotypic compounds (PyH)2[Nb6Cl12]Cl6, (PyH)2[Nb6Br12]Cl6, (PyH)2[Ta6Cl12]Cl6, and (PyH)2[Ta6Br12]Cl6 containing the [Me6X12]4+ cluster have been prepared and characterized by analysis, GUINIER-diagrams, magnetic behaviour, IR and UV absorption spectra, and solution behaviour.Some information on (PyH)2[Ta6Cl12]Br6 is given.(PyH)2[Ta6Cl12]Cl6 and (PyH)2[Ta6Cl12]Br6 are obviously identical with „(C5H5N)H3Ta3Cl9“ and “(C5H5N)H3[Ta3Cl6Br3]” earlier described by LINDNER und FEIT.
    Notes: Die neuen, isotypen Pyridiniumsalze (PyH)2[Nb6Cl12]Cl6, (PyH)2[Nb6Br12]Cl6, (PyH)2[Ta6Cl12]Cl6 und (PyH)2[Ta6Br12]Cl6 mit der [Me6X12]4+-Gruppe wurden dargestellt und durch Analysen, GUINIER-Diagramme, magnetisches Verhalten, Absorptionsspektren vom IR- bis UV-Bereich und durch ihr Lösungsverhalten charakterisiert.Für (PyH)2[Ta6Cl12]Br6 werden ebenfalls Angaben gemacht.(PyH)2[Ta6Cl12]Cl6 und (PyH)2[Ta6Cl12]Br6 sind offenbar mit den früher von LINDNER und FEIT als „(C5H5N)H3Ta3Cl9“ und „(C5H5N)H3[Ta3Cl6Br3]“ beschriebenen Verbindungen identisch.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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