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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The product prepared following the method of GOEHRING and FELDMANN from H2S2O3 and S2Cl2 is not a „spectrum“ of different salts as stated by WEITZ and BECKER, but really K2S6O6, which is also prepared from H2S2O3 and HNO2. Tetrasulfane-disulfonate does not only exist in the neutral form K2S6O6, but also in a „acid“ form with a part of the potassium - nonstoichiometrically - replaced by H+. The two forms have different shape and X-ray spectra.
    Notes: Bei dem nach GOEHRING und FELDMANN aus H2S2O3 und S2Cl2 dargestellten Produkt handelt es sich nicht, wie von WEITZ und BECKER angegeben, um ein „Spektrum“ verschiedener Salze, sondern um einheitliches K2S6O6, wie es auch aus H2S2O3 und HNO2 erhalten wird. Tetrasulfan-disulfonat existiert neben der neutralen Form K2S6O6 noch in einer „saueren“ Form, bei der ein Teil des Kaliums - nichtstöchiometrisch - durch H+ ersetzt ist. Die beiden Formen unterscheiden sich in Aussehen und Röntgenspektrum voneinander.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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