ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Protonation and Solvation of Weak Organic Bases. IV. 1H-N.M.R. Spectroscopic Determination of the Basicity of Aliphatic KetonesFrom protonation ratios for a series of methyl and ethyl alkyl ketones 1 - 13 with gradually branched alkyl groups in the H2O-H2SO4 system, determined by 1H-n.m.r. spectroscopy, basicity and solvation parameters are systematically estimated by application of extrapolation procedures based on the Hammett acidity function H0 or the excess acidity X.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19883300117