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Gibberelline. CIII. Synthese von 8-Amino-gibbanen (1984)

Hung, Ph. D. ; Adam, G.

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 253-258

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ISSN: 0021-8383

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Gibberellins. CIII. Synthesis of 8-Amino-gibbanesFor investigations of the structure-activity relationships of gibberellin phytohormones the synthesis of 8-amino-gibbanes is described. The reaction pathway involves condensation of gibberellin C (1a) and its methylester 1b with primary amines to the corresponding azomethins 1c-11 followed by stereoselective NaBH4-reduction to 8α-amino gibbanes 2a-2r.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prac.19843260209

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