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Über die Pyrolyse von Pent-1-en-4,4,5,5,5-d5 (1983)

Kopinke, F.-D. ; Bach, G. ; Ondruschka, B. ; [et al.]

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 699-707

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ISSN: 0021-8383

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: On the Pyrolysis of Pent-1-ene-4,4,5,5,5-d5The distribution of deuterium in the main products of thermal decomposition of pent-1-ene-4,4,5,5,5-d5 at 550 to 650°C was studied and interpreted. The results include conclusions on kinetic isotope effects, on relative reactivities of different C-H-bonds, on the proportion of terminal and nonterminal addition of methyl radicals, and on the importance of a radical isomerisation reaction. It was shown that the molecular decomposition (Retro-En-Reaction) cannot successfully compete with the radical way in the temperature range above 600°C

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prac.19833250504

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