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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 551-560 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-α-Bromacetyl-coumarines as Synthones for Heterocyclic Substituted Coumarines3-α-Bromacetyl-coumarines 2 react easily and in high yields with thiourea and thioamide derivatives 3 and 5, resp., to 4-coumar-3′-yl-thiazoles 4 and 6, resp., as well as with N,N-disubstituted thioamides 11 and N,N,N′,N′-tetraalkylthiourea 12 to 5-coumar-3′-yl-oxathioliumsalts 13 and 14, respectively. In a two-step reaction 2 can be transformed by reaction with aniline 17 to 4-coumar-3′-yl-imidazoles 21 and 5-coumar-3′-yl-oxazoliumsalts 22, resp., via aminoketone intermediates 18.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
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