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Aldehyde, tert. Amine bzw. Acetale aus Amidacetalen und Grignardverbindungen (1980)

Walther, H. ; Haase, L. ; Gross, H. ; [et al.]

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 322 (1980), S. 902-908

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ISSN: 0021-8383

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Aldehydes, tert. Amines or Acetales from Amidacetales and Grignard-CompoundsAmidacetales 1 or -mercaptales 9 respectively react with Grignard-agents dependent on molar ratio by exchange of methoxy- or methylthio group via not isolable O,N- or S,N-acetales to the corresponding aldehydes 4 or the tert. amines 3. Starting from bicyclic amidacetales 6 aldehydes or bis-β-hydroxyethylamines 8 are formed. By quaternisation of the amidacetal-nitrogen followed by reaction with Grignard-agents the corresponding O,O-acetales are formed.

Additional Material: 4 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prac.19803220607

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