ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The Reaction of N-Sulfinylamines with Isocyanides and Synthesis of 2,5-Diaryl-3,4-diarylimino-1,2,5-thiadiazolidin-S-oxidesN-Sulfinylamines 1 react with isocyanides 2 to give isocyanates 3, isothiocyanates 6, and especially 2,5-diaryl-3,4-diarylimino-1,2,5-thiadiazolidin-S-oxides 7.This new heterocyclic ring system 7 can also be synthesized in high yields by a cyclization reaction of tetraarylated oxalic amidines 9 with thionyl chloride.The acid catalyzed hydrolysis of the heterocyclic compounds 7 leads to oxalic anilides 8, the hydrolysis with alkali forms amidines 9. The amidine 9a reacts with N-sulfinyl-p-toluenesulfonamide 11 to give an open chained adduct 12.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19803220213
