ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
About Some Correlations between Electron-Impact-Induced Fragmentations and Properties of Organic MoleculesThe most important theoretical conceptions in organic mass-spectrometry are discussed and compared. By consideration of special cases of single, competitive and consecutive reaction models and their graphical presentation it is possible to demonstrate some consequences of the QET useful for the qualitative interpretation and the understanding of the formation process of a mass-spectrum. The validity and the limits of the physical-organic theory of mass-spectra is examined from the point of view of the QET. A method to estimate the relative strength of chemical bonds in ions from fragmentation behaviour, including rearrangement, is proposed.
Additional Material:
12 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19793210105