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Dimerisation of caffeine (1985)

Horman, Ian ; Dreux, Bernard

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 68 (1985), S. 72-75

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Displacements of 1H-NMR chemical shifs for caffeine in D2O solution as a function of concentration conform to the behaviour expected for pure dimer formation according to the equilibrium 2(caffeine)⇄(caffeine)2 with a statistical probability of at least 95%. Confidence limits reported earlier for the dimerisation constant of caffeine represent the real statistical dispersion in the experimental data and do not reflect a systematic error such as tetramer formation.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19850680109

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