ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The molecular ions from three isomeric cyclanones isomerize to the ethyl-2-cyclohexanone ion prior to C2H4 elimination. With D- and 18O-labelled compounds it is shown by Mass Analyzed Ion Kinetic Energy Spectroscopy (MIKES.) that both isomerization and C2H4 loss are specific processes. By high resolution collisional activation spectra it is shown that the resultant fragment ion [C6H10O]\documentclass{article}\pagestyle{empty}\begin{document}$ 1^{+ \atop \dot{}} $\end{document} (m/z = 98) differs in structure from the cyclohexanone molecular ion.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19810640839