ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The displacements of double bonds by basic catalysts (N-lithioethylene diamine with an excess of ethylene diamine, potassium t-butylate in dimethylsulfoxide, benzyl-sodium in boiling xylene) are studied on p-menthenes and p-menthadienes. The isomerizations of p-menthadienes are accompanied by dehydrogenation. A representative mechanism of isomerization and dehydrogenation according to the catalyst is proposed for limonene.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19740570422