ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the reactions of the complexes C3H5MC5H5 (M = Ni, Pd) with tertiary phosphites P(OR)3 to give M[P(OR)3]4 have been investigated. For M = Ni and R = C2H5, there results a third-order rate law whereas for M = Pd and R = C6H5 a second-order rate law is observed. Possible mechanistic implications of the kinetic data will be discussed.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19730560154