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Zur Deutung der thermodynamischen Daten von Komplexbildungsreaktionen I (1968)

Anderegg, G.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 51 (1968), S. 1856-1863

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The free enthalpy of complex formation, corrected for the involved change of the number of particles, is described as a sum: δGta + δGtu (= δG - δGm), which permits the separation of the temperature dependent terms. Following Gurney, it is supposed that the temperature dependent free enthalpy δGta varies in the same way as the reciprocal of the dielectric constant of the solvent. This model furnishes some relations which permit a correct description of the complex formation in terms of an electrovalent and of a nonelectrovalent interaction.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19680510806

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