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A kinetic study of the reaction of chlorine and fluorine atoms with HC(O)F at 295±2 K (1997)

Meagher, Robert J. ; Mcintosh, Mark E. ; Hurley, Michael D. ; [et al.]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 29 (1997), S. 619-625

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Using relative rate techniques the reactions of chlorine and fluorine atoms with HC(O)F have been determined to proceed with rate constants of k1 = (1.9 ± 0.2) × 10-15 and k2 = (8.3 ± 1.7) × 10-13 cm3 molecule-1 s-1, respectively. Stated errors reflect statistical uncertainty; possible systematic uncertainties could add additional 10% and 20% ranges to the values of k1 and k2, respectively. Experiments were performed at 295 ± 2 K and 700 torr total pressure of air. The results are discussed with respect to the design and interpretation of laboratory studies of the atmospheric chemistry of CFC replacements. © 1997 John Wiley & Sons, Inc.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

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