ALBERT — All Library Books, journals and Electronic Records Telegrafenberg

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

Rate constants of elementary reactions in the high temperature system of nitric oxide and hydrogen (1976)

Ando, H. ; Asaba, T.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 8 (1976), S. 259-275

add to mindlist on the mindlist

Details

ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The consumption of nitric oxide in the shock-heated nitric oxide, hydrogen, and argon system had been studied and modeled as the chain-branching process containing the reaction H + NO ⇀ N + OH (k3) as a slow-branching step. Through the computer simulation method the authors clarified the role of the initiation reaction H2 + NO ⇀ HNO + H (k1) in the system and obtained the rate constants of k1 and k3 as k1 = 1013.5±0.15 exp (-55.2 kcal/RT) and k3 = 1013.7±0.15 exp (-48.7 kcal/RT) (cm3/mole·sec), respectively. k1 was one order larger than the value obtained in the flame experiment by Halstead and Jenkins.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550080208

	Location	Call Number	Expected	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit