ISSN:
0268-2605
Keywords:
Hydrogenation
;
hydroformylation
;
rhodium(I)
;
platinum(II)
;
aminoalkylphosphines
;
catalyst
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hydrogenation of α-acetamidocinnamic acid with chiral aminomethylphosphine complexes of rhodium(I), [Rh(cyclo-octa-1, 5-diene) {(R2PCH2)2NR1}]-PF6 (R = Ph or Cy, R1 = D(+)-CHMePh, L-CHMeCO2Et, (R)(+)-bornyl) shows no asymmetric induction. The hydroformylation of styrene using the catalyst mixture [PtCl2(P-P)]/SnCl2 shows asymmetric induction with up to 31% enantiomeric excess of 2-phenyl-propanol being observed.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590070710