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Enoletherepoxide und ihre Reaktionsprodukte mit Nucleophilen (1993)

Meyer, Claudia ; Spiteller, Gerhard

Weinheim : Wiley-Blackwell

Liebigs Annalen 1993 (1993), S. 17-21

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ISSN: 0170-2041

Keywords: Enol ethers ; Dioxirane, dimethyl ; Epoxides ; Acetals ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Enol Ether Epoxides and Products Resulting from Their Reaction with Nucleophiles1,2-Epoxydecyl pentyl ether (9a) was synthesized by treatment of 1-decenyl pentyl ether (5) with diemthyldioxirane (8). The enol ether epoxide 9a, characterized by its mass, 1H- and 13C-NMR spectra, reacts readily with hydride, O-, S- and N-nucleophiles. Similar reactions are expected to take place in the organism after biological oxidation of plasmalogens to their epoxides. This hypothesis is verified by detection of mixed acetals after tissue workup.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.199319930105

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