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Enzym-katalysierte Reaktionen, 13. Eine neue, effiziente Synthese von Fagomin (1992)

Effenberger, Franz ; Null, Volker

Weinheim : Wiley-Blackwell

Liebigs Annalen 1992 (1992), S. 1211-1212

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ISSN: 0170-2041

Keywords: Fagomine ; Enzymes ; Transketolase ; Carbohydrates ; Yeast transketolase ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Enzyme-Catalyzed Reactions, 13. - A New, Efficient Synthesis of Fagomine2-Deoxy-L-threo-5-hexulosonitrile (4) is obtained in excellent chemical yield by yeast transketolase (EC 2.2.1.1)-catalyzed reaction of racemic 3-hydroxy-4-oxobutyronitrile [(R/S)-2] with lithium hydroxypyruvate (3). Catalytic hydrogenation of 4 exclusively gives fagomine (7).

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.1992199201201

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