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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1019-1025 
    ISSN: 1434-193X
    Keywords: Silver ; Methylene-oxolanes ; O-Heterocycles ; Enol ethers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Silver salts which have a basic counter-ion are efficient catalysts for the regiospecific intramolecular addition of various acetylenic alcohols. Silver carbonate in aromatic solvent proved to be the best catalyst. Alkynols in which the two reacting parts of the molecule are relatively close together in space required only catalytic amounts of silver ion, while others cyclize readily with stoichiometric quantities. This heterocyclization reaction provides a mild and convenient access to 2-methylene-oxolanes or oxanes.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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