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The Vinylogous Michael Reaction - A Novel Perspective for Biaryl Synthesis (1999)

Christoffers, Jens ; Mann, Alexander

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 2511-2514

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ISSN: 1434-193X

Keywords: Biaryls ; Homogeneous catalysis ; Iron ; Michael additions ; Quinones ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Dienol tautomers 2 of 2-acceptor-substituted cycloalkenones 1 undergo an iron(III)-catalyzed reaction sequence - formally a vinylogous Michael reaction - with benzoquinone derivatives 5 to yield products 6, 7 and 9, which are easily converted into highly functionalized biaryl compounds.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

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