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Catalytic Transfer Hydrogenation of Ketones with KHCr(CO)5/HCO2H/Et3N Systems (1999)

Brunet, Jean-Jacques ; Chauvin, Remi ; Leglaye, Pascale

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 713-716

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ISSN: 1434-1948

Keywords: Chromates ; Catalytic transfer hydrogenation ; Hydrogenations ; Reductions ; α,β-Unsaturated ketones ; Asymmetric synthesis ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In the presence of a HCO2H/Et3N (1:1) mixture, KHCr(CO)5 is an efficient catalyst precursor for the transfer hydro-genation of ketones in THF at room temperature. KHCr(CO)5 is also a stoichiometric reagent for the selective reduction of the carbon-carbon double bond of α,β-unsaturated ketones.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

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