ISSN:
0009-2940
Keywords:
Metallacycles
;
Palladium catalysis
;
Domino reactions
;
Polycyclic ring systems
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Palladacycles are discussed as the key intermediates of some important preparative ring forming reactions; their reactivity depends strongly on the ring size. The existence of 5-membered palladacycles, and even 4-membered palladacycles, is now firmly established, whereas the knowledge of 6-membered and larger palladacycles is based mainly on mechanistic considerations. The role of 5-membered palladacycles as catalysts is described briefly.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971301104