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Enantioselective Catalysis. New Chiral Expanded Phosphanes Derived from Substituted Deltacyclenes (1997)

Brunner, Henri ; Reimer, Alfred

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1495-1498

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ISSN: 0009-2940

Keywords: Deltacyclenes ; Deltacyclanes ; P-H addition reactions ; Chiral phosphanes ; Enantioselective catalysis ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The suitability of enantiomerically pure deltacyclenes as building blocks in the synthesis of expanded phosphanes was examined. Different substituted deltacyclenes were irradiated with diphenylphosphane and three bisphosphanyl derivatives. With these P—H addition reactions, new chiral deltacyclane-derived phosphorus ligands were synthesized. They were tested in the Rh-catalyzed asymmetric hydrogenation of (Z)-(ã)-N-acetamidocinnamic acid and in the Pd-catalyzed asymmetric allylation of 1,5-dimethylbarbituric acid.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19971301023

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