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Alkali Metal Polyphosphides in Low Dimensions: Synthesis and Structure of [(CH3)4N]2RbP7(NH3) and [(C2H5)4N]Cs2P11 (1996)

Korber, Nikolaus ; von Schnering, Hans Georg

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 155-159

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ISSN: 0009-2940

Keywords: Polyphosphides ; Heptaphosphanortricyclane ; Undecaphosphatrishomocubane ; Ufosane ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Partial exchange of the alkali metal ions for tetraalkylammonium cations of Rb3P7 and Cs3P11 in liquid ammonia results in the formation of [(CH3)4N]2RbP7(NH3) (1) and [(C2H5)4N]Cs2P11 (2). The crystal structures reveal the existence of one-dimensional 1∞[RbP7]2- chains in the former and two-dimensional 2∞[Cs2P11]- layers in the latter compound. The nortricyclane cage in 1 is distorted by one-sided coordination to the Rb ions in a manner that can be related to the valence tautomerism of the free P73- anion.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19961290208

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