ISSN:
0009-2940
Keywords:
Cyclophanes
;
Naphthalenophanes
;
McMurry reaction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The (1,4)naphthalenophanes 6a, 6b, 7a, and 7b were synthesized regiospecifically in two steps from the appropriate α,β-di-1-naphthylalkanes by a Friedel-Crafts acetylation of the two naphthalene groups followed by cyclization/dimerization of the resulting diketones by a McMurray reaction. The macrocyclic naphthalenophanes 6a and 6b exist in solution as a mixture of conformers while 7a and 7b were identified as the anti isomers.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270629